新戊二醇的成分
新戊二醇（Neopentyl glycol）
一、新戊二醇简介
产品名称: 新戊二醇(Neo，或NPG)
产品英文名: Neopentyl glycol2,2-Dimethyl-1,3-propanediol
化学名称（Chemical Name）： 2,2-二甲基-1,3-丙二醇
分子式(Formula): C5H12O2
分子量(Molecular Weight): 104.15
CAS号（CAS No.)： 126-30-7
物化性质(Physical and Chemical Properties)：
白色结晶固体，无臭，具有吸湿性。熔点124～130℃。沸点210℃。密度（21℃）1.06g/cm3。闪点129℃。自燃点399℃。升华温度210℃。易溶于水、低级醇、低级酮、醚和芳烃化合物等。
毒性防护：
低毒。大鼠经口LD50≥6400mg/kg。小鼠经口LD50为3200～6400mg/kg。对皮肤刺激性小。但大量饮用会刺激中枢神经，引起呕吐、疲倦、昏睡、呼吸困难、震颤、肾脏充血和出血、肝脏脂肪病变、闭尿、支气管炎和肺炎等症状，严重者甚至导致死亡。
产品用途：
主要用于生产不饱和树脂、聚脂粉末涂料、无油醇酸树脂、聚氨脂泡沫塑料、即弹性体的增塑剂、合成增塑剂、表面活性剂、绝缘材料、印刷油墨、阻聚剂、合成航空润滑油油品添加剂等。另外，在医药行业也有所应用。同时，新戊二醇还是优良的溶剂，可用于芳烃和环烷基碳氢化合物的选择分离。
质量标准： HG/T2309-92
包装储运：
固态采用袋装，内层为塑料袋、外层为编织袋，25KG/袋。
液态采用镀锌铁桶包装，25kg/桶。
贮存于阴凉、通风处，防晒、防热、防潮。按一般化学品规定储运。
二、新戊二醇的三大生产流派。
1、国际上，新戊二醇生产主要有三大流派，其中歧化工艺（甲醇法）是中国特有的。
国内新戊二醇的生产商基本成三足鼎立的局面，大体分为三派：
加氢工艺：吉化巴斯夫。
歧化工艺（甲醇法）：以山东省化工研究院为代表的甲醇法工艺，该工艺为最新歧化改进工艺。
歧化工艺（水溶法）：以富丰柏斯托为代表的水溶法工艺。
2、特点介绍：（1）加氢工艺有流程短，收率高，纯度高，成本低等优点。缺点：加氢工艺投资大，对外部环境要求高，产品价格高。目前在国内市场，加氢工艺的NPG比较多，如BSF,韩国LG，日本三菱，伊斯曼等。其中巴斯夫和韩国LG在新戊二醇市场的争夺比较激烈。
（2）歧化工艺（甲醇法）克服了投资大的缺点，质量远在国标之上，且产品价格低，在很多行业性价比是比较高的。缺点：与加氢工艺相比，纯度低。该工艺的甲酸钠是一大亮点。颜色纯白，杂质少，干基含量在99%以上，且不易结块，质量上比合成法的和季戊四醇副产的都要好。在国际市场，该工艺的甲酸钠一枝独秀。
（3）歧化工艺（水溶法）投资也不大，质量和甲醇法的差不多，只是更容易结块。副产甲酸钠与甲醇法的区别比较大，颜色暗灰或灰色，纯度低，其主要卖点是从里面能提取新戊二醇。
中文名称： 二溴新戊二醇
中文别名： 2,2-二(溴甲基)-1,3-丙二醇二溴新戊醇
英文名称： 2,2-bis(bromomethyl)-1,3-propanediol
英文别名： Dibromoneopentyl glycol2,2-Bis(bromomethyl)propane-1,3-diol
CAS号： 3296-90-0
EINECS号： 221-967-7
分子式： C5H10Br2O2
分子量： 261.9397
InChI： InChI=1/C5H10Br2O2/c6-1-5(2-7,3-8)4-9/h8-9H,1-4H2
分子结构：
密度： 1.977g/cm3
熔点： 112-114℃
沸点： 370.9°C at 760 mmHg
闪点： 178.1°C
蒸汽压： 5.16E-07mmHg at 25°C
物化性质：
熔点112-114°C。
产品用途：
一种反应性阻燃剂，使用后能达到更加严密的阻燃效果
http://www.canto.hk/product/html/?390.html
生产单位有：广拓化学（上海）有限公司 上海嘉辰工贸有限公司 上海海化国际贸易有限公司 上海爱蝶实业有限公司
CAS号：6846-50-0
EINECS号：229-934-9
分子式：C16H30O4
分子量：286.407
密度：0.951g/cm3
沸点：280°C at 760 mmHg
闪点：154.6°C
蒸汽压：0.00388mmHg at 25°C
物化性质：沸点,℃ 280熔点,℃ -70闪点,℃ 143密度,20℃/4℃ 0.945折光率,nD20 1.430
产品用途：用作塑料制品的增塑剂,无毒,相溶性好
分子式C5H10O2分子量102.13精确质量102.13PSALogP基础参数CAS号：5057-99-8分子式：C5H10O2分子量：102.13中文名称(±)-反-1，2-环戊。
在自然界存在极少，只在糖及其类似物的各种发酵物中得到少量低级脂肪二醇。如乙二醇，1，3-丙二醇、2，3丁二醇等，但未发现环二醇和芳香二醇。
2,2-Dimethyl-1,3-propanediol, 99%
Section 1 - Chemical Product and Company Identification
MSDS Name: 2,2-Dimethyl-1,3-propanediol, 99%
Synonyms: Neopentyl glycol
Company Identification:
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name: % EINECS#
126-30-7 2,2-Dimethyl-1,3-propanediol 99% 204-781-0
Hazard Symbols: XI
Risk Phrases: 41
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Risk of serious damage to eyes.Moisture sensitive.
Potential Health Effects
Eye: Causes redness and pain. May cause eye irritation and possible damage.
Skin: May cause skin irritation. Causes redness and pain.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid.
Notes to Physician:
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.
Section 7 - Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 126-30-7:
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Chunks
Color: white crystalline chunks
Odor: Not available
pH: Not available
Vapor Pressure: 1 mm Hg @ 65 deg C
Viscosity: mPas 150C deg C
Boiling Point: 208 deg C @ 760.00mm Hg ( 406.40°F)
Freezing/Melting Point: 123 - 127 deg C
Autoignition Temperature: 375 deg C ( 707.00 deg F)
Flash Point: 107 deg C ( 224.60 deg F)
Explosion Limits: Lower: 1.40 vol %
Explosion Limits: Upper: 18.80 vol %
Decomposition Temperature: Not available
Solubility in water: freely soluble in alcohol and ether
Specific Gravity/Density: 1.0600g/cm3
Molecular Formula: HOCH2C(CH3)2CH2OH
Molecular Weight: 104.15
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials Oxidizing agents, acid chlorides, acid anhydrides.
Hazardous Decomposition Products Carbon monoxide, carbon dioxide.
Hazardous Polymerization Will not occur.
Section 11 - Toxicological Information
RTECS#: CAS# 126-30-7: TY5775000
LD50/LC50: RTECS: Not available. Other: Oral, rat: LD50 >6400 mg/kg
Carcinogenicity: 2,2-Dimethyl-1,3-propanediol - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Mutagenicity: Ames-test: negative.
Section 12 - Ecological Information
Ecotoxicity: Fish: Leuciscus idus: EC/LC50: >500 mg/l48 h
Daphnia: EC/LC50: >500 mg/l48 h
Algae: EC/LC50: >500 mg/l72 h
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
IATA IMO RID/ADR
Shipping Name: Not available Not available Not available
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 126-30-7: 1
Canada
CAS# 126-30-7 is listed on Canada's DSL List
US Federal
TSCA
CAS# 126-30-7 is listed on the TSCA Inventory.
Section 16 - Other Information
MSDS Creation Date: 9/13/1996
Revision #1 Date 10/24/2000
Revisions were made in Sections: General revision.
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages.
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中文名称
新戊二醇二丙烯酸酯
中文别名
2,2-二甲基-1,3-丙烷二基二丙烯酸酯二丙烯酸新戊二醇酯2-丙烯酸-2,2-二甲基-1,3-丙二酯新戊二醇二丙烯酸酯(含稳定剂甲氧基氢醌)
英文名称
Neopentyl
glycol
diacrylate
英文别名
viscoat2472,2-Dimethyl-1,3-propanediol
DiacrylateNEOPENTGLYCOL
DIACRYLATE1,3-Bis(acryloyloxy)-2,2-dimethylpropanedimethylolpropanediacrylateNeopentyl
glycol
dianeopentylglycol
diacrylateNEOPENTANEDIOLDIACRYLATENeopentyl
Glycol
Diacrylate2,2-Dimethylpropanediacrylate2,2-dimethyltrimethyleneacrylate2-propenoic
acid
2,2-dimethyl-1,3-propanediyl
estersr247LIGHT
ACRYLATE
NP-ANeopentylene
glycol
diacrylate
CAS号
2223-82-7
上游原料
CAS号
中文名称
126-30-7
2,2-二甲基-1,3-丙二醇
292638-85-8
丙烯酸甲酯
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